应用 Umicore预催化剂，用于不对称和交叉偶联催化用作以下反应的催化剂：氧化烯化反应仲醇的C-C键裂解苯酚衍生物的邻位C-H烯化反应吡啶的氧化环化反应苯甲酰胺与醛通过sp2C-H 键的直接官能化发生氧化邻位酰化反应酰胺化反应还原性烷基化反应五甲基环戊二烯基铑 (III) 氯化物二聚体可作为催化剂 用于：氧化烯化反应、仲醇的C-C 键裂解、苯酚衍生物的邻位 C-H 烯化反应、吡啶的氧化环化反应、苯甲酰胺与醛通过 sp2C-H 键的直接官能团化反应与醛类发生氧化邻位酰化反应、还原烷基化反应['Umicore预催化剂，用于不对称和交叉偶联催化 Description Pentamethylcyclopentadienylrhodium(III) chloride dimer can be used as a catalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactionsUmicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for:Oxidative olefination reactionsC-C bond cleavage of secondary alcoholsOrtho C-H olefination of phenol derivativesOxidative annulation of pyridinesOxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2C-H bondAmidation reactionsReductive alkylation reactions